Hydrogen induced cracking of low strength steels in geothermal fluids keith a. The mechanism of failure by hydrogen induced cracking in an. Defects hydrogen cracks in steels identification twi. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. The boltloaded specimen was subjected to both acid and electrochemical cell environments in order to produce hydrogen. Presentation on hydrogen induced cracking and sulfide stress cracking by denzil d souza.
According to iso 15156, hydrogeninduced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. Cosasco provides hydrogen monitoring solutions for corrosion control such as hydrogen blistering hydrogen induced cracking hic on steel. It is often assumed that hic is just a subcategory of sulfide stress cracking. Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. May 22, 2018 hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan.
Hic test, hydrogen induced cracking test, step wise cracking. The hic may promote one mode of fracture in an alloy rather than another form normally observed in benign environments. Refers to mechanical damage of metal caused by the presenceinteraction with hydrogen can be classified in to following types 1 hydrogen blistering 2 hydrogen embrittlement 3 hydrogen attack 4 decarburization hydrogen damage. This is hydrogen induced cracking by synergis education on vimeo, the home for high quality videos and the people who love them. Each form can build up enough pressure to produce internal cracks. Hydrogen induced cracking hic assessment in a gas processing plant case study mohammed a abufour, mohammad. It primarily occurs in high strength low alloy steels. The results of the hydrogen induced cracking tests presented in this podcast can serve as a benchmark for the future development of high performance navy steels. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Lichti, david m firth and annette d karstensen mpt solutions, po box 310, lower hutt, new zealand k. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism.
Hydrogen induced cracking test for naval steels american. The trapped molecular hydrogen in the mill laminations or voids will have high internal pressure which will cause hydrogen blistering or cracking. Hydrogen induced cracking hic there are a variety of forms of wet h2s cracking. Hydrogen induced crackinghydrogen induced cracking 2. The molecular form of hydrogen cannot diffuse and is stable. Hydrogen induced cracking of low strength steels in. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. Antihydrogen induced cracking material engineering. When the crystal lattice is in contact or is saturated with atomic hydrogen, the mechanical. Hydrogen combines with carbon within the alloy and forms methane. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6.
A comparative study of hydrogeninduced cracking resistances of. Hydrogen cracking its causes, costs and future occurrence. At intermediate stage adsorbed hydrogen atoms hads are present. Although hydrogen induced cracking and stress corrosion cracking are similar phenomena, both types of damage are usually described and treated separately. The role of hydrogen in the mechanism of stress corrosion cracking has been known since the 1970s so that preventative measures have since been introduced.
In this issue, the characteristic features and principal causes of hydrogen cracks are described. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Simply put, hydrogen induced cracking damage increases as the level of hydrogen sulphide increases. Published by welding technology institute of australia wtia, silverwater, nsw, australia, 1999.
Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. Effect of microstructure on low temperature hydrogen induced. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. That means the hydroxyle ions decharge separately one by one. Hydrogen delayed cracking of highstrength weldable steels 7 these reactions take place in two steps.
Elements hic tests evaluate material susceptibility to hydrogen induced cracking in a sour environment in accordance with nace tm0284. Hydrogen induced cracking hic is a mechanical fracture caused by the penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular hydrogen in the internal interface between nonmetallic inclusion and base material. The paper looks at the problem of hydrogen cracking both in general fabrication and with particular reference to. Hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. Pdf hydrogen induced cracking safe materials operating. Hydrogen induced cracking steel features, applications and. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. Hydrogen induced cracking tests of high strength steels.
For example, hydrogen embrittlement was observed to occur in the timonbal,30 tivcralsn,31 and tivfeal32 alloys, well below the hydrogen concentration. Processes or conditions involving wet hydrogen sulfide, i. Corrosionpedia what is hydrogeninduced cracking hic. Specificationsgrades asmeastm saa 516 grades 606570. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Hydrogen induced cracking tests of high strength steels and. Hydrogen cracking its causes, costs and future occurrence twi. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Hydrogen induced cracking tests were conducted on high strength steels and nickeliron base alloys using the constant displacement boltloaded compact specimen. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Hydrogen atoms are very reactive and combine with almost all elements. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry.
Prior to 2003, hydrogen induced cracking hic testing was not incorporated into nace mr0175 iso 15156 and generally was not required for mildly sour environments i. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hydrogeninduced cracking is caused by nascent hydrogen atoms ho, usually produced in aqueous hydrogen sulphide h2s. One key difference between hydrogen embrittlement and stress corrosion cracking, although very similar in many aspects, is their reaction to cathodic protection.
Hydrogen atoms produced, for example, by the corrosion reaction of iron, usually combine to form hydrogen gas molecules. Hydrogen cracking is also named as toe cracking or underbead cracking due to its location of occurrence. Hydrogen cracking in weld metals the effects of composition, hydrogen content and preheat on weld metal cracking are studied by m. Stress oriented hydrogen induced cracking sohic behavior of heat affected zone haz of l360mcs steel in wet h2s environment was studied by separating crack, sem and eds. Hydrogen induced cracking hic on steel for corrosion. In the present work, an api x70 pipeline steel was electrochemically charged with hydrogen for different durations in order to find crack nucleation and propagation sites. Jun 05, 2017 hydrogen atoms are very reactive and combine with almost all elements. For haz hydrogen cracking to occur, it is necessary for the hydrogen to migrate into the heat affected zone, which takes time. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from excessive internal hydrogen pressure.
Atomic hydrogen diffuses inside the metal and causes localized deformation, or even destroys the walls of the vessel. A schematic presentation of the various stages of m23c6 carbide growth in aisi 304. Hydrogen blistering occurs when hydrogen atoms diffuse into the steel, and hydrogen gas nucleates at internal defects and inclusions, forming voids which eventually generate enough pressure to locally rupture the metal. Refers to mechanical damage of metal caused by the presenceinteraction with hydrogen can be classified in to following types 1 hydrogen blistering 2 hydrogen embrittlement 3 hydrogen attack 4 decarburization hydrogen damage 3. Damage due to hydrogen embrittlement and stress corrosion. Prior to 2003, hydrogen induced cracking hic testing was not incorporated into nace mr0175 iso 15156 and generally was not required for mildly. Hydrogen induced cracking hic is a failure mechanism. Hydrogen induced blistering when hydrogen is absorbed into metal and diffuses inward, it can precipitate as molecular hydrogen, at laminations, or inclusionmatrix interfaces. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. In the case of a crystal lattice becoming saturated. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Pdf hydrogen induced cracking safe materials operating limits. Hydrogen induced crack resistant hic steel plate brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock.
Hydrogeninduced cracking, or hydrogen embrittlement, is a chemical phenomenon that causes metal alloys to fracture due to a buildup of. May 19, 2009 hic is prevalent in wet h 2 s environments, which is often known as sour service and such cracking over a prolonged period of time without inspection, will reach a critical point and the steel component i. Hic testing apparatus is provided with specially made rack to keep the samples with minimum surface contact and all the specimens can be viewed during the test period easily. Cathodic protection is one of the most effective methods of corrosion protection, however, it does not prevent the diffusion of hydrogen into the steel component. Weld metal hydrogen cracking in pipeline girth welds, proc. Hydrogen induced cracking test tank test methods nace tm0284 astm g39 material of construction polypropylene, pvc, or glass capacities up to 55 liters cortest offers a variety of different hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on a metal sample in a hydrogen enriched. If so, share your ppt presentation slides online with. Atomic hydrogen, and not the molecule, is the smallest atom and it is small enough to diffuse readily through a metallic structure. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Preheating to avoid hydrogen cracking hydrogen cracking may also be called cold cracking or delayed cracking. A program to study the effects of composition, hydrogen con tent and cooling rate on hydrogen cracking in weld metal has been car ried out. Understanding hydrogen induced cold cracking in welds.
Understanding hydrogen induced cold cracking in welds published on april 26, 2017 april 26, 2017 998 likes 49 comments. Hydrogen induced cracking test instrument is supplied with standard size of 12l x 12w x 9h. This can occur during elevatedtemperature thermal treatments and in service during electroplating, contact with maintenance chemicals, wet h2s, corrosion reactions, cathodic protection, and operating in highpressure hydrogencontaining environments. During welding, hydrogen is induced due to the moisture and organic compounds by the usage of cold cellulosic electrodes. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Introduction to welding technology is the property of its rightful owner. Hydrogen cracking may also be called cold cracking or delayed cracking. Dec 01, 2000 the role of hydrogen in the mechanism of stress corrosion cracking has been known since the 1970s so that preventative measures have since been introduced. Corrosion testing laboratory,hydrogen induced cracking,hic. Hydrogen gas introduced thinning thinning main crack main crack microcrack formed crack linkage. Hic is often fairly innocuous but not always, while sohic is a type of cracking that can easily lead to failure. Hydrogen induced cracking hic assessment in a gas processing plant.
Although hydrogeninduced cracking and stress corrosion cracking are similar phenomena, both types of damage are usually described and treated separately. Mechanism of failure by hydrogen induced cracking hic in pipeline steel has not been extensively investigated in the past. Hydrogen blistering a special case of hydrogen damage is known as hydrogen blistering. Hydrogen induced cracking hic there are several categories of hydrogen phenomena that are localized in nature. Hic test, hydrogen induced cracking test, step wise.
The mechanism of failure by hydrogen induced cracking in. Hydrogeninduced cracking results from atomic hydrogen being absorbed by solid metals. Susceptibility to hydrogeninduced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the. Stressoriented hydrogeninduced cracking of l360qs steel. Hydrogen embrittlement and stress corrosion cracking. Hydrogen induced cracking hic in the oil and gas industry. The european pipeline research group eprg has initiated a project to compare full scale hydrogen induced cracking hic test results 1sided exposure with laboratory hic test results 6sided exposure of the same materials with a view to generating acceptance criteria for sweet service steels that could be applied to milder sour conditions. Naceastm g193 1 includes the following description of hydrogen blistering. Hydrogen induced cracking hic from advanced ndt solutions. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Hydrogen induced cracking is associated with absorption of hydrogen and a delayed time to failure incubation time during which hydrogen diffuses into regions of high triaxial stress. According to iso 15156, hydrogen induced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. Mechanisms that have been proposed to explain embrittlement include the formation of brittle hydrides, the creation of voids that can lead to bubbles and pressure buildup within a material and e. Hydrogen induced cracking steel features, applications.